A Chemist Speaks
In the New Year Bottlings List 1996,
the thorny question of writing tasting notes was touched upon.
There are two styles: tight-lipped and florid. These roughly
correspond to the two recognised ways of approaching sensory
analysis of any kind, viz: objective/analytical and subjective /
hedonic. The whole subject arouses strong feelings, and the
battle is fought mainly within the wine trade, which has a much
more highly developed tasting vocabulary than we do. The tight-lipped school eschews any show of emotion, metaphor
and simile. Michael Broadbent, possibly the leading authority on
wine tasting and author of several books on the subject,
maintains that "it is ridiculous to be over-expressive about
quite ordinary wines". He is supported by the great Hugh
Johnson, for whom the effusions of the florid school smack of bad
English: "Some wines do not require that sort of
imagery". But the florid school is currently winning the day. Jilly
Goolden is the doyenne. For her the restrained tasting notes of
the past are 'a fat lot of use' when it comes to getting the
taste of wine over to a wider public. She prefers to create
'taste pictures' with similes drawn from everyday life. Her co-presenter on The Food Programme, Oz Clarke,
believes the tight-lipped approach is a hang-over from the days
when the wine trade was dominated by upper-class public
schoolboys who had been brought up to distrust any display of
emotion or enthusiasm. He is even happy that the many followers
of The Food Programme 'take the piss' (his words) out of his and
Jilly Goolden's approach. We openly admit to being hedonic (as in 'hedonism', the search
for pleasure) when we describe our malt whiskies. There is much
to be enthusiastic about, and, as the Society's founder Pip Hills
wrote in Scots on Scotch, the notes represent
"...the joint subjectivity of our tasting panel".
Nevertheless, our notes are worthless to you, dear member, if
they bear little or no relation to what is actually there in the
glass. Bearing this in mind, we were delighted to be able to help
Colin Brown, a Manufacturing Scientist undertaking an Investigation
by Analytical Chemistry of Compounds Affecting Flavour in Single
Malt Whiskies, for Napier University, Edinburgh, with the
support of United Distillers. He writes: The investigation, which is
continuing, began by identifying the relative concentrations of
compounds known to be extracted from the cask during maturation
('cask-extractive congeners') and a group of those which arise
from the raw materials and during production ('volatile phenolic
congeners'). It went on to make a correlation between these and
the perceived flavour of the finished product.* Four samples of
whisky were considered, affording a regional spread. They were:
Caol Ila (Islay), Scapa (Orkney), Rosebank (Lowland) and Balvenie
(Speyside). "Cask-extractive congeners are of great
importance to the overall flavour as well as the aroma and colour
of the finished beverage. Whisky casks are traditionaly treated
to thermally degrade the internal surface of the cask, by firing
and charring, for three major reasons: The results revealed that all four samples contained similar
levels of the compound furfural, which is associated
with a general 'whisky flavour'. The unmistakably woody flavour
in the Scapa sample is attributable to syringealdehyde,
which is also present in Caol Ila, although the dominating
flavours of the Islay whisky are discussed later. The Balvenie
chromatogram reveals a high level of ellagic acid, a
compound known for its pungent odour and flavour. The number and
relatively large abundance of lignin degradation products
in the Caol Ila sample would suggest that a heavily charred oak
cask was used for the maturation process. The presence of 5-hydroxymethyl
furfural in Caol Ila would allow the taster to expect a
slightly reddish tint to the whisky. "Volatile phenolic congeners'
primary source is from the peated malt used in whisky production.
So it was not surprising to discover that the Caol Ila sample had
a large number present and in concentrations greatly in excess of
the other whiskies under investigation. "The presence of phenol at 2.1 parts per million
(ppm), was almost five times that for Rosebank, 20 times that for
Balvenie and 200 times greater than that found in Scapa. Phenol
has a medicinal taste and therefore would be expected to be
present in an Islay whisky. Guaiacol, known for its
smoky and phenolic flavour, was detected in concentrations of 1.2
ppm in Caol Ila, but was barely detectable in the others. Further
investigation showed that the levels of compounds responsible for
'tarry' and 'disinfectant' flavours (m-, p- and o-cresol)
were evident in the Islay sample but relatively low in Rosebank,
very low in Balvenie and not detectable in Scapa. However,
similar concentrations of the compound eugenol
(perceived as having a flavour not dissimilar to that of cloves)
were determined in both Scapa and Caol Ila. All of the whiskies
investigated contained varying concentrations of 4-ethyl
phenol and 2,5-xylenol, which co-eluted and could
not be determined separately. Both of these substances have a
powerful 'whisky' flavour." Mr Brown concludes: "Many other compounds were determined analytically during
this investigation, however their individual impact on flavour is
considered less important than their contribution to the overall
flavour of each whisky. These analyses are intended to give an
insight into the complex chemistry of single malt whiskies and
the impact which each of the many hundereds of compounds has on
the characteristics of the finished product." With respect to chemists - and subject, of course, to your
comments - I think we will stick to hedonic descriptions! *For those of you who understand the lingo, the compounds
were determined by the use of a 'direct-injection reversed-phase
High Performance Liquid Chromatographic technique (HPLC),
employing gradient elution and either uv/vis (diode array)
detection or fluorescence'. Charlie Maclean Unless otherwise noted, all information in this site © The Scotch Malt Whisky Society, Edinburgh, Scotland, 1997.The Scientific Approach
"Single malt whiskies are chemically complex and are known
to contain several hundreds of individual components (congeners)
including a variety of alcohols, aldehydes, acids, esters and
phenols, as well as carbonyl-, sulphur- and nitrogen-containing
compounds. Many of these contribute to the flavour of a whisky
and the relative concentrations of each are dependent upon
variations in raw materials and production methods. Consequently,
each single malt whisky is discernable from any other, including
those produced at a neighbouring distillery."